A quick peek into the spectroscopic determinations behind its bioinorganic structure and mechanism
نویسنده
چکیده
منابع مشابه
New Perspectives on Thiamine Catalysis: From Enzymic to Biomimetic Catalysis
This paper is a brief review of the detailed mechanism of action of thiamine enzymes, based on metal complexes of bivalent transition and post-transition metals of model compounds, thiamine derivatives, synthesized and characterized with spectroscopic techniques and X-ray crystal structure determinations. It is proposed that the enzymatic reaction is initiated with a V conformation of thiamine ...
متن کاملSpectroscopic methods in bioinorganic chemistry: blue to green to red copper sites.
A wide variety of spectroscopic methods are now available that provide complimentary insights into the electronic structures of transition-metal complexes. Combined with calculations, these define key bonding interactions, enable the evaluation of reaction coordinates, and determine the origins of unique spectroscopic features/electronic structures that can activate metal centers for catalysis....
متن کاملSynthetic and Spectroscopic Characterization of Organotin(IV) Complexes of Biologically Active Schiff Bases Derived from Sulpha Drugs
A number of diorganotin(IV) complexes with Schiffbase have been synthesized and characterized by elemental analysis, conductance measurements, molecular weight determinations, infrared, electronic and multinuclear magnetic resonance ((1)H, (13)C and (119)Sn NMR) spectral data. The molar conductivity data shows non-electrolytic nature of complexes. The bidentate nature of the ligands is inferred...
متن کاملDirect Numerical Simulation of the Wake Flow Behind a Cylinder Using Random Vortex Method in Medium to High Reynolds Numbers
Direct numerical simulation of turbulent flow behind a cylinder, wake flow, using the random vortex method for an incompressible fluid in two dimensions is presented. In the random vortex method, the primary variable is vorticity of the flow field. After generation on the cylinder wall, it is followed in two fractional time step in a Lagrangian system of coordinates, namely convection and diffu...
متن کاملA delve into the exploration of potential bacterial extremophiles used for metal recovery
A multitude of microbes are involved in the solubilisation of minerals and metals as this approach offers numerous advantages over traditional methods. This strategy is preferred as it is eco-friendly and economical, thus overcoming the drawbacks of the traditional approach of pyrometallurgy. Many different types of bacteria are employed in the process of Bioleaching, which are collectively gro...
متن کامل